This paper presents gas compositions and H-, O-isotope compositions of sulfide- and quartz-hosted fluid inclusions, and S-, Pb-isotope compositions of sulfide separates collected from the principal Stage 2 ores in Veins 3 and 210 of the Jinwozi lode gold deposit, eastern Tianshan Mountains of China. Fluid inclusions trapped in quartz and sphalerite are dominantly primary. H-and O-isotopic compositions of pyrite-hosted fluid inclusions indicate two major contributions to the ore-forming fluid that include the degassed magma and the meteoric-derived but rock 18O-buffered groundwater. However, H- and O-isotopic compositions of quartz-hosted fluid inclusions essentially suggest the presence of groundwater. Sulfide-hosted fluid inclusions show considerably higher abundances of gaseous species CO2, N2, H2S, etc. than quartz-hosted ones. The linear trends among inclusion gaseous species reflect the mixing tendency between the gas-rich magmatic fluid and the groundwater. The relative enrichment of gaseous species in sulfide-hosted fluid inclusions, coupled with the banded ore structure indicating alternate precipitation of quartz with sulfide minerals, suggests that the magmatic fluid has been inputted to the ore-forming fluid in pulsation. Sulfur and lead isotope compositions of pyrite and galena separates indicate an essential magma derivation for sulfur but the multiple sources for metallic materials from the mantle to the bulk crust.
文章通过详细的野外地质调查和系统的岩石化学、稀土元素、微量元素及硅、氧同位素等研究,探讨了羊蹄子山-磨石山钛矿区无矿白色硅质岩和富钛硅质岩的成因及形成地质构造环境。研究结果表明,呈厚层状产出的无矿白色硅质岩具较高的SiO2、Al2O3含量及Al/(Al Fe Mn)、Al2O3/(Al2O3 Fe2O3)比值,稀土元素总量很低,其北美页岩标准化配分模式为向右倾的曲线,无明显铈异常和铕异常,表明其形成于受陆源影响的大陆边缘构造环境;赋矿岩系中薄层状富钛硅质岩的TiO2、Fe2O3、Cu、V含量较高,但Al/(Al Fe Mn)、Al2O3/(Al2O3 Fe2O3)比值较低,稀土元素总量较高,北美页岩标准化曲线为明显左倾型-平坦型,具弱的负铈异常,表明其形成于洋脊及附近环境。两种硅质岩的δ30Si值为变化较小的负值,与热水沉积和某些生物成因硅质岩的硅同位素组成相似,两者的δ18O值范围和平均值均相似。两类硅质岩的成因及形成构造环境不同,富钛硅质岩的地球化学特征表明,该矿床的形成与本区元古宙海底火山热液喷流作用有关。 相似文献
